Volumetric properties of chloroalkanes + amines mixtures: Theoretical analysis using theERAS-Model

Página do item simplificado
dc.contributor.authorTorres R.B.
dc.contributor.authorHoga H.E.
dc.contributor.authorMagalhaes J.G.
dc.contributor.authorVolpe P.L.O.
dc.date.accessioned2019-08-20T00:12:04Z
dc.date.available2019-08-20T00:12:04Z
dc.date.issued2009
dc.description.abstractIn this study, experimental data of excess molar volumes of {dichloromethane (DCM), or trichloromethane (TCM) + n-butylamine (n-BA), or +s-butylamine (s-BA), or +t-butylamine (t-BA), or +diethylamine (DEA), or +triethylamine (TEA)} mixtures as a function of composition have been used to test the applicability of the extended real associated solution model (ERAS-Model). The values of the excess molar volume were negative for (DCM + t-BA, or +DEA, or +TEA and TCM + n-BA, or +s-BA, or +DEA, or +TEA) mixtures and present sigmoid curves for (DCM + n-BA, or +s-BA) mixtures over the complete mole-fraction range. The agreement between theoretical and experimental results is discussed in terms of cross-association between the components present in the mixtures. © 2009 Springer Science+Business Media, LLC.
dc.description.firstpage1202
dc.description.issuenumber4
dc.description.lastpage1212
dc.description.volume30
dc.identifier.citationTORRES, Ricardo Belchior; HOGA, H. E.; MAGALHÃES, Jucélio Gobbi; VOLPE, Pedro Luiz Onófrio. Volumetric Properties of Chloroalkanes + Amines Mixtures: Theoretical Analysis Using the ERAS Model. International Journal of Thermophysics, v. 30, n. 4, p. 1202-1212, 2009.
dc.identifier.doi10.1007/s10765-009-0632-0
dc.identifier.issn0195-928X
dc.identifier.urihttps://repositorio.fei.edu.br/handle/FEI/1738
dc.relation.ispartofInternational Journal of Thermophysics
dc.rightsAcesso Restrito
dc.subject.otherlanguageAmines
dc.subject.otherlanguageChloroalkanes
dc.subject.otherlanguageERAS-Model
dc.subject.otherlanguageVolumetric properties
dc.titleVolumetric properties of chloroalkanes + amines mixtures: Theoretical analysis using theERAS-Model
dc.typeArtigo
fei.scopus.citations2
fei.scopus.eid2-s2.0-70349745231
fei.scopus.subjectButylamines
fei.scopus.subjectChloroalkanes
fei.scopus.subjectCross-association
fei.scopus.subjectDiethylamines
fei.scopus.subjectERAS-Model
fei.scopus.subjectExcess molar volumes
fei.scopus.subjectExperimental data
fei.scopus.subjectN-butylamine
fei.scopus.subjectSigmoid curves
fei.scopus.subjectSolution model
fei.scopus.subjectTrichloromethane
fei.scopus.subjectTriethylamines
fei.scopus.subjectVolumetric properties
fei.scopus.updated2024-12-01
fei.scopus.urlhttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=70349745231&origin=inward
Arquivos
Coleções
Artigos