Volumetric properties of binary mixtures of (water + organic solvents) at temperatures between T = 288.15 K and T = 303.15 K at p = 0.1 MPa

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dc.contributor.authorTorres R.B.
dc.contributor.authorMarchiore A.C.M.
dc.contributor.authorVolpe P.L.O.
dc.date.accessioned2019-08-20T00:12:04Z
dc.date.available2019-08-20T00:12:04Z
dc.date.issued2006
dc.description.abstractIn this work, densities of binary mixtures of {water + formamide (FM), or + N,N-dimethylformamide (DMF), or + dimethylsulfoxide (DMSO), or + N,N-dimethylacetamide (DMA), or + 1,4-dioxane}, have been determined under atmospheric pressure as a function of composition and temperature using a vibrating-tube densimeter. The temperatures studied were T = (288.15, 293.15, 298.15, and 303.15) K. The excess molar volumes ( VmE ), calculated from density data, are negative over the whole mole fraction range for the temperature range studied. The VmE values have been fitted to Redlich-Kister polynomial equation and others volumetric properties were calculated. The partial molar volumes at infinite dilution of each component ( over(V, ̄)i∞ ) have been determined using three different methods. © 2005 Elsevier Ltd. All rights reserved.
dc.description.firstpage526
dc.description.issuenumber5
dc.description.lastpage541
dc.description.volume38
dc.identifier.citationTORRES, Ricardo Belchior; MARCHIORE, Ana Carolina M; VOLPE, Pedro Luiz Onófrio. Volumetric Properties of Binary Mixtures of (Water + Organic Solvents) at Temperatures between T = 288.15 K and T = 303.15 K at p = 0.1 Mpa. Journal of Chemical Thermodynamics, v. 38, n. 5, p. 526-541, 2006.
dc.identifier.doi10.1016/j.jct.2005.07.012
dc.identifier.issn0021-9614
dc.identifier.urihttps://repositorio.fei.edu.br/handle/FEI/1732
dc.relation.ispartofJournal of Chemical Thermodynamics
dc.rightsAcesso Restrito
dc.subject.otherlanguage1,4-Dioxane
dc.subject.otherlanguageDimethylsulfoxide
dc.subject.otherlanguageFormamide
dc.subject.otherlanguageN,N-Dimethylacetamide
dc.subject.otherlanguageN,N-Dimethylformamide
dc.subject.otherlanguageVolumetric properties
dc.subject.otherlanguageWater
dc.titleVolumetric properties of binary mixtures of (water + organic solvents) at temperatures between T = 288.15 K and T = 303.15 K at p = 0.1 MPa
dc.typeArtigo
fei.scopus.citations111
fei.scopus.eid2-s2.0-33646229561
fei.scopus.subject1,4-Dioxane
fei.scopus.subjectDimethylsulfoxide
fei.scopus.subjectFormamide
fei.scopus.subjectN,N-Dimethylacetamide
fei.scopus.subjectN,N-Dimethylformamide
fei.scopus.subjectVolumetric properties
fei.scopus.updated2024-10-01
fei.scopus.urlhttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=33646229561&origin=inward
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