Density and Derived Properties of Binary Mixtures Containing {2-(Dimethylamino)ethyl Methacrylate + Alcohols} at Temperatures from T = (293.15 to 313.15) K and Pressures of up to 35 MPa

dc.contributor.authorMuche D.N.F.
dc.contributor.authorOlivieri G.V.
dc.contributor.authorTorres R.B.
dc.date.accessioned2019-08-20T00:12:05Z
dc.date.available2019-08-20T00:12:05Z
dc.date.issued2019
dc.description.abstract© 2019 American Chemical Society. In this study, experimental density data (ρ) for binary liquid mixtures containing {2-(dimethylamino)ethyl methacrylate (DMAEMA) + methanol, or + ethanol, or + 1-propanol, or + 1-butanol, or + 1-pentanol} have been measured over the entire composition range at temperatures from T = (293.15 to 313.15) K and pressures of up to 35 MPa. Density measurements were obtained using an Anton Paar DMA 4500 vibrating-tube densimeter coupled to an external Anton Paar DMA HP high-pressure measuring cell. The experimental results for density have been fit to the Tait-Tammann equation and used to calculate the isothermal compressibility (κ T ), the thermal expansion coefficient (α p ), and the internal pressure (π). The excess molar volume (Vm E ) values have still been calculated and used to test the applicability of the extended real associated solution model (ERAS model) and the Prigogine-Flory-Patterson theory (PFP Theory). The thermodynamic results suggest that structural and chemical effects must outweigh physical effects.
dc.description.firstpage1909
dc.description.issuenumber5
dc.description.lastpage1921
dc.description.volume64
dc.identifier.citationMuche, Dereck Nills Ferreira; OLIVIERI, G. V.; TORRES, Ricardo Belchior. Density and Derived Properties of Binary Mixtures Containing {2-(Dimethylamino)ethyl Methacrylate + Alcohols} at Temperatures from T = (293.15 to 313.15) K and Pressures of up to 35 MPa. JOURNAL OF CHEMICAL AND ENGINEERING DATA, v. 64, n. 5, p. 1909-1921, 2019.
dc.identifier.doi10.1021/acs.jced.8b00975
dc.identifier.issn1520-5134
dc.identifier.urihttps://repositorio.fei.edu.br/handle/FEI/1750
dc.relation.ispartofJournal of Chemical and Engineering Data
dc.rightsAcesso Restrito
dc.titleDensity and Derived Properties of Binary Mixtures Containing {2-(Dimethylamino)ethyl Methacrylate + Alcohols} at Temperatures from T = (293.15 to 313.15) K and Pressures of up to 35 MPa
dc.typeArtigo
fei.scopus.citations6
fei.scopus.eid2-s2.0-85062890630
fei.scopus.subject2-(dimethylamino)ethyl methacrylate
fei.scopus.subjectAssociated solution models
fei.scopus.subjectBinary-liquid mixtures
fei.scopus.subjectExcess molar volumes
fei.scopus.subjectIsothermal compressibility
fei.scopus.subjectPrigogine-Flory-Patterson (PFP)
fei.scopus.subjectThermal expansion coefficients
fei.scopus.subjectVibrating tube densimeters
fei.scopus.updated2024-02-01
fei.scopus.urlhttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85062890630&origin=inward
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