Density and Derived Properties of Binary Mixtures Containing {2-(Dimethylamino)ethyl Methacrylate + Alcohols} at Temperatures from T = (293.15 to 313.15) K and Pressures of up to 35 MPa
dc.contributor.author | Muche D.N.F. | |
dc.contributor.author | Olivieri G.V. | |
dc.contributor.author | Torres R.B. | |
dc.date.accessioned | 2019-08-20T00:12:05Z | |
dc.date.available | 2019-08-20T00:12:05Z | |
dc.date.issued | 2019 | |
dc.description.abstract | © 2019 American Chemical Society. In this study, experimental density data (ρ) for binary liquid mixtures containing {2-(dimethylamino)ethyl methacrylate (DMAEMA) + methanol, or + ethanol, or + 1-propanol, or + 1-butanol, or + 1-pentanol} have been measured over the entire composition range at temperatures from T = (293.15 to 313.15) K and pressures of up to 35 MPa. Density measurements were obtained using an Anton Paar DMA 4500 vibrating-tube densimeter coupled to an external Anton Paar DMA HP high-pressure measuring cell. The experimental results for density have been fit to the Tait-Tammann equation and used to calculate the isothermal compressibility (κ T ), the thermal expansion coefficient (α p ), and the internal pressure (π). The excess molar volume (Vm E ) values have still been calculated and used to test the applicability of the extended real associated solution model (ERAS model) and the Prigogine-Flory-Patterson theory (PFP Theory). The thermodynamic results suggest that structural and chemical effects must outweigh physical effects. | |
dc.description.firstpage | 1909 | |
dc.description.issuenumber | 5 | |
dc.description.lastpage | 1921 | |
dc.description.volume | 64 | |
dc.identifier.citation | Muche, Dereck Nills Ferreira; OLIVIERI, G. V.; TORRES, Ricardo Belchior. Density and Derived Properties of Binary Mixtures Containing {2-(Dimethylamino)ethyl Methacrylate + Alcohols} at Temperatures from T = (293.15 to 313.15) K and Pressures of up to 35 MPa. JOURNAL OF CHEMICAL AND ENGINEERING DATA, v. 64, n. 5, p. 1909-1921, 2019. | |
dc.identifier.doi | 10.1021/acs.jced.8b00975 | |
dc.identifier.issn | 1520-5134 | |
dc.identifier.uri | https://repositorio.fei.edu.br/handle/FEI/1750 | |
dc.relation.ispartof | Journal of Chemical and Engineering Data | |
dc.rights | Acesso Restrito | |
dc.title | Density and Derived Properties of Binary Mixtures Containing {2-(Dimethylamino)ethyl Methacrylate + Alcohols} at Temperatures from T = (293.15 to 313.15) K and Pressures of up to 35 MPa | |
dc.type | Artigo | |
fei.scopus.citations | 6 | |
fei.scopus.eid | 2-s2.0-85062890630 | |
fei.scopus.subject | 2-(dimethylamino)ethyl methacrylate | |
fei.scopus.subject | Associated solution models | |
fei.scopus.subject | Binary-liquid mixtures | |
fei.scopus.subject | Excess molar volumes | |
fei.scopus.subject | Isothermal compressibility | |
fei.scopus.subject | Prigogine-Flory-Patterson (PFP) | |
fei.scopus.subject | Thermal expansion coefficients | |
fei.scopus.subject | Vibrating tube densimeters | |
fei.scopus.updated | 2024-02-01 | |
fei.scopus.url | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85062890630&origin=inward |