Volumetric properties of binary mixtures of ethers and acetonitrile: Experimental results and application of the Prigogine-Flory-Patterson theory

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dc.contributor.authorTorres R.B.
dc.contributor.authorOrtolan M.I.
dc.contributor.authorVolpe P.L.O.
dc.date.accessioned2019-08-20T00:12:04Z
dc.date.available2019-08-20T00:12:04Z
dc.date.issued2008
dc.description.abstractIn this work, densities of binary mixtures of {acetonitrile + di-n-butyl ether (DNBE), or + tetrahydrofuran (THF), or + 1,4-dioxane (DIO), or + di-isopropyl ether (DIPE)}, have been determined under atmospheric pressure as a function of composition and temperature using a vibrating-tube densimeter. The temperatures studied were T = (288.15, 293.15, 298.15, and 303.15) K. The excess molar volumes (VmE), calculated from density data, are negative over the whole mole fraction range for the temperature range studied. The partial molar volumes at infinite dilution of each component (over(V, -)i∞) have been determined using three different methods. The experimental results have been used to test the applicability of the Prigogine-Flory-Patterson (PFP) theory. © 2007 Elsevier Ltd. All rights reserved.
dc.description.firstpage442
dc.description.issuenumber3
dc.description.lastpage459
dc.description.volume40
dc.identifier.citationTORRES, Ricardo Belchior; ORTOLAN, Marco I; VOLPE, Pedro Luiz Onófrio. Volumetric Properties of Binary Mixtures of Ethers and Acetonitrile: Experimental Results and Application of the Prigogine-Flory-Patterson Theory. Journal of Chemical Thermodynamics, v. 40, p. 442-459, 2008.
dc.identifier.doi10.1016/j.jct.2007.09.007
dc.identifier.issn0021-9614
dc.identifier.urihttps://repositorio.fei.edu.br/handle/FEI/1734
dc.relation.ispartofJournal of Chemical Thermodynamics
dc.rightsAcesso Restrito
dc.subject.otherlanguage1,4-Dioxane
dc.subject.otherlanguageAcetonitrile
dc.subject.otherlanguageDi-isopropyl ether
dc.subject.otherlanguageDi-n-butyl ether
dc.subject.otherlanguagePFP theory
dc.subject.otherlanguageTetrahydrofuran
dc.subject.otherlanguageVolumetric properties
dc.titleVolumetric properties of binary mixtures of ethers and acetonitrile: Experimental results and application of the Prigogine-Flory-Patterson theory
dc.typeArtigo
fei.scopus.citations35
fei.scopus.eid2-s2.0-39749164486
fei.scopus.subjectDi-isopropyl ether
fei.scopus.subjectDi-n-butyl ether
fei.scopus.subjectPFP theory
fei.scopus.subjectTetrahydrofuran
fei.scopus.subjectVolumetric properties
fei.scopus.updated2024-03-04
fei.scopus.urlhttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=39749164486&origin=inward
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