Engenharia de Materiais
URI permanente desta comunidadehttps://repositorio.fei.edu.br/handle/FEI/17
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6 resultados
Resultados da Pesquisa
- Investigation on the effect of a compatibilizer on the fatigue behavior of PP/coir fiber composites(2011) Bettini S.H.P.; Antunes M.C.; Magnabosco R.The mechanical behavior of polypropylene (PP) and 30 wt% coir fiber reinforced PP composites, with and without compatibilizer, were assessed through monotonic (tensile and bending) and cyclic (fatigue) tests. Fatigue load controlled tests were conducted under tension loads at a frequency of 6 Hz. The fracture mechanism was accompanied by surface fracture analyses using both optical microscopy and scanning electron microscopy. The compatibilizer used was the PP grafted with maleic anhydride. The compatibilized composites exhibited longer fatigue life times. It was also concluded that the presence of coir fibers changed the preferential fatigue mechanism, because the fracture mechanism in PP was mainly caused by heat generated by viscous effects during solicitation (thermal fatigue), whereas in the compatibilized and noncompatibilized PP/coir composites the predominant fracture mechanism was mechanical fatigue. However, thermal fatigue was also observed in the composites, especially in the noncompatibilized ones. © POLYM. ENG. SCI., 2011. Copyright © 2011 Society of Plastics Engineers.
- Correlating different techniques in the thermooxidative degradation monitoring of high-density polyethylene containing pro-degradant and antioxidants(2018) Antunes M.C.; Agnelli J.A.M.; Babetto A.S.; Bonse B.C.; Bettini S.H.P.© 2018 Elsevier LtdDifferent techniques were used to assess the effect of a primary and a secondary antioxidant, separately, and in combination with a pro-degradant (manganese stearate) on the thermooxidative abiotic degradation of high-density polyethylene (HDPE). The parameters measured over time at three temperatures (60, 70 and 80 °C) were variation in carbonyl index (CI), by means of infrared spectroscopy; reduction in tensile strain at break, by means of mechanical testing; reduction in molar mass distribution by means of size exclusion chromatography (SEC). Regardless of the presence of primary or secondary antioxidants, the same levels of degradation were attained. However, contrary to the secondary antioxidant, the primary antioxidant significantly increased induction time of HDPE oxidative degradation processes, evidenced by the shift in the “CI versus time” curve and by the considerably longer time for the strain at break to reach minimal values. Increase in thermooxidation temperature reduced induction time significantly.
- Investigation on the use of coir fiber as alternative reinforcement in polypropylene(2010) Bettini S.H.P.; Bicudo A.B.L.C.; Augusto I.S.; Antunes L.A.; Morassi P.L.; Condotta R.; Bonse B.C.Polypropylene/coir fiber composites were prepared according to an experimental statistical design, in which the independent variables, coir fiber, and compatibilizer content, were varied. The compatibilizer used was maleic anhydride grafted polypropylene (PP-g-MA). Compatibilizer free composites were also prepared. Composites were processed in a corotating twin-screw extruder and submitted to mechanical and morphological analyses. The effects of the independent variables on the mechanical properties were assessed through tensile strength, elongation at break, flexural modulus, and impact strength. The morphological properties were assessed by scanning electron microscopy (SEM). The results indicated the need for using compatibilizers in the composites due to the incompatibility of PP and coir fiber. The variable with the strongest effect on the properties was coir content, whose increase caused increase in tensile strength, impact strength and elastic modulus, and decrease in elongation at break. The presence of PP-g-MA was fundamental to achieving the aforementioned results. The effect of increasing compatibilizer content was only observed for the elastic modulus. © 2010 Wiley Periodicals, Inc.
- Effect of sawdust surface treatment and compatibilizer addition on mechanical behavior, morphology, and moisture uptake of polypropylene/sawdust composites(2010) Bettini S.H.P.; Bonse B.C.; Melo E.A.; Munoz P.A.R.Polypropylene/sawdust composites were investigated to assess the effect of sawdust surface treatment and compatibilizer addition on polymer/fiber adhesion. Two silane coupling agents were used for sawdust surface treatment: vinyl-tris (2-methoxyethoxy) silane and (3- aminopropyl)triethoxysilane. Maleic anhydride grafted polypropylene was used as compatibilizer. Composites were prepared in a corotating twin-screw extruder coupled to a Haake torque rheometer and submitted to tensile and bending tests as well as scanning electron microscopy (SEM). Moisture uptake tests were also performed. Results showed that incorporation of untreated sawdust to polypropylene (PP) caused reduction in composite tensile strength and increase in stiffness. When the only treatment used was surface modification with silane coupling agents, no significant changes were observed in mechanical properties. However, when compatibilizer was added to the composites, tensile strength was increased, and % elongation at break reduced, indicating improved system compatibility. The composite presenting the highest increase in tensile strength was that containing sawdust treated with amino silane in addition to the compatibilizer. SEM analyses corroborated the mechanical property results. © 2009 Society of Plastics Engineers.
- Fatigue life of coir fiber reinforced PP composites: Effect of compatibilizer and coir fiber contents(2013) Antunes M.C.; Moraes D.V.O.; Magnabosco R.; Bonse B.C.; Bettini S.H.P.The fatigue behavior of polypropylene/coir fiber composites was investigated. Composites were prepared according to an experimental statistical design, in which the independent variables coir fiber and compatibilizer content were varied. The compatibilizer used was maleic anhydride grafted polypropylene (PP-g-MA). Compatibilizer free composites were also prepared. Composites were prepared in a corotating twin-screw extruder and the mechanical behavior of polypropylene/coir fiber composites were assessed through monotonic (tensile) and cyclic (fatigue) tests. Fatigue load controlled tests were conducted under tension-tension loads at a frequency of 6 Hz. The fracture mechanism was accompanied by surface fracture analyses using scanning electron microscopy (SEM). The results indicated the need for using compatibilizer in the composites; however, increase in compatibilizer content did not affect composite fatigue lifetime. Coir content was the variable with the strongest effect on composite properties; increasing this variable caused significant increase in fatigue life. © 2013 Society of Plastics Engineers.
- Abiotic thermo-oxidative degradation of high density polyethylene: Effect of manganese stearate concentration(2017) Antunes M.C.; Agnelli J.A.M.; Babetto A.S.; Bonse B.C.; Bettini S.H.P.© 2017 Elsevier LtdThe effect of pro-degradant manganese (Mn) stearate concentration on the oxidative abiotic degradation of high-density polyethylene (HDPE) was investigated in thermo-oxidative tests at three temperatures (60, 70 and 80 °C) over time. Degradation monitoring was carried out, by determining carbonyl indices (CI), using infrared spectroscopy (IR), and by assessing molar masses and their distributions, using size exclusion chromatography (SEC) and tensile tests to assess mechanical properties. Deconvolution analyses of the absorbance bands obtained in the carbonyl region were performed to quantify the functional groups originated from degradation. Similar levels of degradation (equivalent molar mass and oxidation values) were obtained regardless of the investigated manganese concentration (50, 200 and 400 ppm). However, the results indicate that increasing Mn concentration may reduce the induction time for carbonyl formation. Deconvolution of the carbonyl region in IR spectra (between 1800 and 1650 cm−1) indicates that the addition of Mn results in increase in the concentration of oxidized functional groups (ketones, carboxylic acids, lactones, etc.) and that relationship between these groups varies depending on whether manganese stearate is present or not.