Heterogeneous catalyzed isomerization of turpentine oil by ordered mesoporous materials like M41S structures

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dc.contributor.advisorOrcidhttps://orcid.org/0000-0001-6524-1233
dc.contributor.advisorOrcidhttps://orcid.org/0000-0001-8612-7376
dc.contributor.authorSOUSA, L. B. DE
dc.contributor.authorSPERANZA, J. T.
dc.contributor.authorRodrigo Condotta
dc.contributor.authorRodrigo Cella
dc.date.accessioned2023-06-01T06:06:13Z
dc.date.available2023-06-01T06:06:13Z
dc.date.issued2022-07-05
dc.description.abstract© 2022 Canadian Society for Chemical Engineering.Herein, the synthesis of a structure with a porous system similar to that of molecular sieves, MCM-41 and 48 types, with the incorporation of heteroatoms in their synthesis, is reported. The catalytic activity of these materials was tested in the isomerization reaction of turpentine oil to obtain camphene. The best results were obtained with Zn-Al-Si-MCM, a mesoporous material, with a conversion of up to 96% and selectivities of 31% and 22% to camphene and 4-carene, respectively, both of which are bicyclic products. The recycling of the catalyst was also tested, and after three cycles, no significant loss of activity was observed.
dc.identifier.citationSOUSA, L. B. DE; SPERANZA, J. T.; CONDOTTA, R. CELLA, R. Heterogeneous catalyzed isomerization of turpentine oil by ordered mesoporous materials like M41S structures. Canadian Journal of Chemical Engineering, jul. 2023.
dc.identifier.doi10.1002/cjce.24746
dc.identifier.issn0008-4034
dc.identifier.urihttps://repositorio.fei.edu.br/handle/FEI/4805
dc.relation.ispartofCanadian Journal of Chemical Engineering
dc.rightsAcesso Aberto
dc.subject.otherlanguagebiomass
dc.subject.otherlanguagecamphene
dc.subject.otherlanguageisomerization
dc.subject.otherlanguageMCM catalyst
dc.titleHeterogeneous catalyzed isomerization of turpentine oil by ordered mesoporous materials like M41S structures
dc.typeArtigo
fei.scopus.citations0
fei.scopus.eid2-s2.0-85145267329
fei.scopus.subjectBicyclic products
fei.scopus.subjectHeteroatoms
fei.scopus.subjectIsomerisation
fei.scopus.subjectIsomerization reaction
fei.scopus.subjectMCM catalyst
fei.scopus.subjectOrdered mesoporous materials
fei.scopus.subjectPorous system
fei.scopus.subjectTurpentine oil
fei.scopus.subject]+ catalyst
fei.scopus.updated2024-05-01
fei.scopus.urlhttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85145267329&origin=inward
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