Thermodynamic and spectroscopic properties of binary {1-Ethyl-3-methylimidazolium thiocyanate ([EMIM][SCN]) + alcohols} mixtures at T = (298.15 to 308.15) K and p = (0.1 to 40) MPa: Experimental study and modelling

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dc.contributor.authorHAUK, D. B.
dc.contributor.authorRicardo Torres
dc.contributor.authorD'ANGELO, J. V. H.
dc.contributor.authorOrcidhttps://orcid.org/0000-0002-0791-4775
dc.date.accessioned2022-01-12T21:53:43Z
dc.date.available2022-01-12T21:53:43Z
dc.date.issued2021-09-05
dc.description.abstract© 2021 Elsevier LtdIn this study, densities for binary mixtures of {1-Ethyl-3-methylimidazolium thiocyanate ([EMIM][SCN]) + alcohols} have been measured at temperatures from T = (298.15 to 308.15) K and pressures from p = (0.1 to 40) MPa. These results have been used to calculate the excess molar volumes, partial molar volumes, apparent molar volumes and partial molar volumes at infinite dilution. The experimental density data were correlated by using the Tait-Tammann equation to obtain isothermal compressibility and isobaric expansion. Moreover, the values of excess molar volume were used to test the applicability of the Extended Real Associated Solution Model (ERAS Model). In order to elucidate possible structural phenomena, spectroscopic properties (H-NMR, C-NMR and FT-IR) were combined with the thermodynamic results trying to understand the molecular interactions among the unlike components present in the studied systems.
dc.description.volume160
dc.identifier.citationHAUK, D. B.; TORRES, R. Thermodynamic and spectroscopic properties of binary {1-Ethyl-3-methylimidazolium thiocyanate ([EMIM][SCN]) + alcohols} mixtures at T = (298.15 to 308.15) K and p = (0.1 to 40) MPa: Experimental study and modelling. Journal of Chemical Thermodynamics, v. 160, sept. 2021.
dc.identifier.doi10.1016/j.jct.2021.106489
dc.identifier.issn1096-3626
dc.identifier.urihttps://repositorio.fei.edu.br/handle/FEI/3559
dc.relation.ispartofJournal of Chemical Thermodynamics
dc.rightsAcesso Restrito
dc.subject.otherlanguageAlcohols
dc.subject.otherlanguageIonic liquids
dc.subject.otherlanguageModelling
dc.subject.otherlanguageSpectroscopy
dc.subject.otherlanguageVolumetric properties
dc.titleThermodynamic and spectroscopic properties of binary {1-Ethyl-3-methylimidazolium thiocyanate ([EMIM][SCN]) + alcohols} mixtures at T = (298.15 to 308.15) K and p = (0.1 to 40) MPa: Experimental study and modelling
dc.typeArtigo
fei.scopus.citations3
fei.scopus.eid2-s2.0-85105469194
fei.scopus.subjectAlcohol mixtures
fei.scopus.subjectApparent Molar volume
fei.scopus.subjectDensity data
fei.scopus.subjectExcess molar volumes
fei.scopus.subjectModeling
fei.scopus.subjectPartial Molar volume
fei.scopus.subjectPartial molar volumes at infinite dilution
fei.scopus.subjectSpectroscopic property
fei.scopus.subjectThermodynamics property
fei.scopus.subjectVolumetric properties
fei.scopus.updated2024-07-01
fei.scopus.urlhttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85105469194&origin=inward
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