Measurement and correlation of high-pressure volumetric properties of binary mixtures of 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM][NTf2]) with alcohols

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dc.contributor.advisorOrcidhttps://orcid.org/0000-0002-0791-4775
dc.contributor.authorHAUK, D. B.
dc.contributor.authorRicardo Torres
dc.contributor.authorDANGELO, J. V. H.
dc.date.accessioned2023-08-01T06:02:51Z
dc.date.available2023-08-01T06:02:51Z
dc.date.issued2023-10-05
dc.description.abstract© 2023 Elsevier LtdNew experimental data for density-pressure–temperature measurements of binary mixtures of {1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM][NTf2]) + methanol, or + ethanol or + 1-propanol} have been measured using a vibrating tube densimeter at temperatures from T = (298.15 to 308.15) K and pressure range p= (0.1 – 40) MPa. The experimental density results have been correlated by the Tait-Tammann equation with the temperature and composition dependence parameters. The effects of the increase in the alkyl chains of the alcohols, temperature, and pressure on the density and volumetric properties have been analyzed. Moreover, the Extended Real Associated Solution Model (ERAS Model) has been used to correlate the experimental behavior of the excess molar volume of the studied systems.
dc.description.volume185
dc.identifier.citationHAUK, D. B.; TORRES, H.; DANGELO, J. V. H. Measurement and correlation of high-pressure volumetric properties of binary mixtures of 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM][NTf2]) with alcohols. Journal of Chemical Thermodynamics, v. 185, oct. 2023.
dc.identifier.doi10.1016/j.jct.2023.107122
dc.identifier.issn1096-3626
dc.identifier.urihttps://repositorio.fei.edu.br/handle/FEI/4865
dc.relation.ispartofJournal of Chemical Thermodynamics
dc.rightsAcesso Restrito
dc.subject.otherlanguageAlcohols
dc.subject.otherlanguageERAS model
dc.subject.otherlanguageIonic liquids
dc.subject.otherlanguageVolumetric properties
dc.titleMeasurement and correlation of high-pressure volumetric properties of binary mixtures of 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM][NTf2]) with alcohols
dc.typeArtigo
fei.scopus.citations0
fei.scopus.eid2-s2.0-85164262843
fei.scopus.subject1-propanol
fei.scopus.subjectComposition dependence
fei.scopus.subjectERAS model
fei.scopus.subjectHigh pressure
fei.scopus.subjectMeasurements of
fei.scopus.subjectPressure ranges
fei.scopus.subjectTammann equations
fei.scopus.subjectTemperature dependence
fei.scopus.subjectVibrating tube densimeters
fei.scopus.subjectVolumetric properties
fei.scopus.updated2024-07-01
fei.scopus.urlhttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85164262843&origin=inward
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