Repositório do Conhecimento Institucional do Centro Universitário FEI
 

Engenharia de Materiais

URI permanente desta comunidadehttps://repositorio.fei.edu.br/handle/FEI/17

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2016 - 201912020 - 20221

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Periódico: search.filters.ispartof.Journal of Applied Polymer ScienceAssunto: search.filters.subject.mechanical properties

Resultados da Pesquisa

Agora exibindo 1 - 2 de 2
  • N/D
    Artigo 6 Citação(ões) na Scopus
    PA6/PA66/talc composite: Effect of reprocessing on the structure and properties
    (2022-04-05) DOMINGO, G. D.; SOUZA, A. M. C.
    In this study the effect of repeated injection molding cycles on the structure and properties of polyamide 6/polyamide 66/talc (PA6/PA66/talc - 35/35/30) composite was investigated for samples subjected to one, four, and seven processing cycles. Their morphology (scanning electron microscopy), structure (Fourier transform infrared spectroscopy), melt viscosity (melt flow index [MFI]), mechanical (tensile, flexural, impact, and fatigue tests), and thermal properties (differential scanning calorimetry and thermogravimetric analysis tests) were analyzed. The increase in MFI value and the decrease in the maximum decomposition temperature of PA6, observed by TG analysis, for samples subjected to seven processing cycles, indicated a possible reduction in molar mass of the PA6/PA66 matrix. These samples presented a decrease in degree of crystallinity of PA6 and PA66, which was more pronounced for PA6. The reprocessing of the composite did not present changes in the mechanical properties up to the fourth processing cycle, except for fatigue life which presented a 59% reduction. Samples subjected to seven processing cycles presented a decrease in tensile and flexural strength as well as in tensile and flexural modulus. Charpy impact strength of the samples did not significantly change upon reprocessing. The micrographs of the fatigue fractured surfaces indicated that the weak talc-matrix interaction and talc-matrix debonding became more evident with increasing processing cycles.
  • N/D
    Artigo 20 Citação(ões) na Scopus
    ABS/HIPS blends obtained from WEEE: Influence of processing conditions and composition
    (2016) De Souza A.M.C.; Cucchiara M.G.; Ereio A.V.
    © 2016 Wiley Periodicals, Inc.The recycling of acrylonitrile-butadiene-styrene (ABS) and high-impact polystyrene (HIPS) from postconsumer electronic equipment housing was investigated. A preliminary study of shot size and particle size effects on the mechanical properties of ABS/HIPS (50/50) blends obtained directly via injection molding was conducted. Injection-molded specimens of ABS/HIPS blends, obtained at different compositions with or without previous extrusion, were subjected to mechanical, thermal, and morphological testing. Preliminary studies showed that a smaller particle size resulted in higher tensile and impact strength, regardless of the shot size used during injection molding. ABS/HIPS blends obtained using previous extrusion presented a slight increase in Young's modulus and a decrease in elongation at break and impact strength. The increase in glass-transition temperature related to the Polybutadiene (PB) phases of these blends indicated a possible increase in crosslinking structures during extrusion. In addition, these blends showed a coarse and heterogeneous morphology, suggesting that ABS did not completely mix with HIPS. Compared to processing conditions, the blend composition appeared to have a much stronger effect on the mechanical properties. The results obtained suggest the possibility of obtaining ABS/HIPS blends directly via injection molding as long as small ground particles are used.