A new method for obtaining adsorption isotherms on colloidal suspensions via electrokinetic sonic amplitude measurement
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2005-12-06
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GUIMARAES, K. L.
CASTRO, R. H. R.
GOUVEA, D.
CASTRO, R. H. R.
GOUVEA, D.
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Langmuir
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GUIMARAES, K. L.; CASTRO, R. H. R.; GOUVEA, D. A new method for obtaining adsorption isotherms on colloidal suspensions via electrokinetic sonic amplitude measurement. Langmuir, v. 21, n. 25, p. 11645 - 11650, December, 2005.
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The standard methods for obtaining adsorption isotherms on colloidal suspensions are usually very time consuming and involve a large number of steps and assumptions that increase the experimental errors. In this work, an alternative method is proposed to evaluate the adsorption behavior of electrostericstabilized systems based on electrokinetic sonic amplitude signal measurements. The new method, entitled "zeta-sorption", is noticeably less time-consuming when compared to conventional procedures but showed great precision and reliability confirmed by comparison with data obtained from conventional routes on alumina-polyacrylate and alumina-citric acid aqueous suspensions. The experimental conditions that restrict the applicability of the new method were identified and justified by discussing the possible ion exchanges. © 2005 American Chemical Society.