Retardation effect of nanohydroxyapatite on the hydrolytic degradation of poly (lactic acid)

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dc.contributor.authorWATAI, JULIANA SATIE
dc.contributor.authorCALVÃO, PATRÍCIA SCHMID
dc.contributor.authorRIGOLIN, TALITA ROCHA
dc.contributor.authorBETTINI, SILVIA HELENA DO PRADO
dc.contributor.authorSOUZA, ADRIANA
dc.contributor.authorOrcidhttps://orcid.org/0000-0003-1594-8673
dc.date.accessioned2021-10-21T17:58:38Z
dc.date.available2021-10-21T17:58:38Z
dc.date.issued2020-07-07
dc.description.abstractPoly (lactic acid) (PLA) and PLA/nanohydroxyapatite (nHA) composites, containing 2 wt% and 5 wt% of nHA were subjected to in vitro hydrolytic degradation tests in saline phosphate solution at different temperatures (37°C, 48°C, 60°C, and 72°C) to accelerate degradation. Samples were characterized by water uptake, weight loss tests, size exclusion chromatography (SEC), differential scanning calorimetry (DSC), and visual analyses. Arrhenius equation was used to describe the behavior of weight loss as a function of time. The PLA activation energy of weight loss showed to be lower than that of the PLA/nHA composites, indicating that the incorporation of nHA retarded the hydrolytic degradation. The rate and percentage of weight loss increased with increasing temperature. All samples presented a decrease in Tg and an increase in degree of crystallinity as a function of time. Incorporation of nHA retarded this behavior that showed to be more expressive in PLA containing 5 wt% nHA.
dc.description.firstpage2152
dc.description.lastpage2162
dc.description.volume60
dc.identifier.citationWATAI, J. S.; CALVÃO, P. S.; RIGOLIN, T. R.; BETTINI, S. H. DO P.; SOUZA, A. M. C. Retardation effect of nanohydroxyapatite on the hydrolytic degradation of poly (lactic acid). Polymer Engineering and Science, v. 60, p. 2152-2162, 2020.
dc.identifier.doi10.1002/pen.25459
dc.identifier.issn0032-3888
dc.identifier.urihttps://repositorio.fei.edu.br/handle/FEI/3404
dc.relation.ispartofPOLYMER ENGINEERING AND SCIENCE
dc.rightsAcesso Restrito
dc.subjectin vitro hydrolytic degradation tests
dc.subjectnanohydroxyapatite
dc.subjectpoly (lactic acid)
dc.titleRetardation effect of nanohydroxyapatite on the hydrolytic degradation of poly (lactic acid)pt_BR
dc.typeArtigopt_BR
fei.scopus.citations6
fei.scopus.eid2-s2.0-85087610555
fei.scopus.updated2024-03-04
fei.source.urlhttps://onlinelibrary.wiley.com/doi/10.1002/pen.25459
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